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EM Spectrum and Analytical Chemistry

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The EM Spectrum

Development of Spectroscopy instrumentaion.


Spectroscopy use the energy of Electromagnetic Radiation to study matter. Analytical techniques include computer and fiber optics to extend the use of "chemometrics" procedures to build new spectrometers and spectrophotometers - with applications in the field of chemistry and the sciences. Manufacturers harness the interactions of Electromagnetic radiation to separate waves of different frequencies so that the radiation can be measured as a function of frequency or wavelength.

Spectral range and electron transitions


Instrumentation
Type
Radiation Source Frequency Range (Hz) Wavelength Range Type of Transitions
gamma rays    1020 - 1024 <10-12 m nuclear
X-rays   1017 - 1020 0.01nm - 10nm (1 pico meter) inner electron
ultraviolet deuterium lamp 1015 - 1017 400 nm - 1 nm outer electron. Electronic transitions, vibrational fine structure
visible Tungsten lamp 4 - 7.5 x 1014 750 nm - 400 nm
near-infrared Tungsten, dye laser 1 x 1014 - 4 x 1014 2500 nm - 750 nm (2.5 um - 750 nm) outer electron molecular vibrations. Vibrational transitions, rotational fine structure
infrared nerst glower, globar, Xe,Ar, discharge lamp 1013 - 1014 250,000 - 2,500 nm (25um - 2.5 um) outer electron, molecular vibrations. Vibrational transitions, rotational fine structure
microwaves   3 x 1011 - 1013 250,000 - 1,000,000,000 nm (1 mm - 25 um) molecular rotations,electron spin flips*, Rotational transitions
radio waves   <3 x 1011 >1 mm nuclear spin flips*
* energy levels split by a magnetic field.


The Colors of Visible Radiation ¹



Wavelength Range nm Color seen by Instrument
Absorption color
Color seen by Human Eye
Complement color
400 - 465 Violet Yellowish green
465 - 482 Blue Yellow
482 - 487 Greenish blue Orange
487 - 493 Blue green Red orange
493 - 498 Bluish green Red
498 - 530 Green Red purple
530 - 559 Yellowish green Reddish purple
559 - 571 Yellow green Purple
571 - 576 Greenish yellow Violet
576 - 580 Yellow Blue
580 - 587 Yellowish orange Blue
587 - 597 Orange Greenish blue
597 - 617 Reddish orange Blue green
617 - 780 Red Blue green

Applications with Electromagnetic Radiation


These applications consist of all frequencies from low-frequency Radio waves to high energy Gamma rays.
These waves cover technology from communications to Space Exploration.
There is no division between different types of waves. it is a continuous spectrum that blends seamlessly into one another. The wavelengths and frequencies are inversely related to each other.
Electromagnetic waves show wave-like and particle-like properties known as wave particle duality.

Medical imaging x-rays and MRI. Hospitals - look at bones and organs in human body.
Communications Transmit data - radio/TV broadcasting, statellite, internet.
Solar Light from sun - electricity, reduce carbon emissions.
Food processing preserve food - safety and shelf-life. Microwave - cooking.
Forensic analysis - crime fighting.UV light - see blood, finger prints,, law enforcement.
Weather forecasting Meteorology - radar, statellites.
healthcare sterilization by gamma ray and UV light,
Nigh vision Infrared het detector devices.
Non-destructive testing - UV Fluorescence - electromagnetic induction - fiaws in metal structures, cracks and leaks on surfaces.
Art restoration IR and x ray.
Pest control electromagnetic waves target pests without chemicals.
Space exploration radio transmitter between space craft and earth.IR telescopes.

Reference:
1. "Analytical Absorption Spectroscopy", D.B. Judd; M.G. Melon (Ed.)
Chap. 9, Wiley, New York.


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